process-util: move sync() out of freeze()

We are using this for creating userns namespaces, and we really
shouldn't try to sync there. Moreover the use of free() in shutdown code
doesn't need it anyway, since it just sync()ed right before anyway. Only
the third user of freeze() we have actually needs the syc(), hence do it
there and nowhere else.

src/basic/process-util.c

@@ -1624,8 +1624,6 @@ _noreturn_ void freeze(void) {
         /* Make sure nobody waits for us on a socket anymore */
         (void) close_all_fds_full(NULL, 0, false);
 
-        sync();
-
         /* Let's not freeze right away, but keep reaping zombies. */
         for (;;) {
                 siginfo_t si = {};

src/core/main.c

@@ -222,6 +222,7 @@ _noreturn_ static void freeze_or_exit_or_reboot(void) {
         }
 
         log_emergency("Freezing execution.");
+        sync();
         freeze();
 }